Luminescence tin live defined equally the radiations emitted past times a molecule or an atom on provide to ground country from excited country afterward initial absorption of energy. Both fluorescence in addition to phosphorescence are type of photoluminescence which involves absorption of unloose energy in addition to excitation of atom to higher unloose energy score followed past times emission of electromagnetic radiations (or provide to depression unloose energy state). In both, the emitted photon (light) has lower unloose energy than the absorbed photon in addition to emission occurs at a longer wavelength than the incident light. The major divergence is the duration for each procedure to tumble out afterward the initial absorption of low-cal of right wave length.
Fluorescence vs Phosphorescence
Fluorescence | Phosphorescence |
It is the absorption of unloose energy past times atoms or molecules followed past times immediate emission of low-cal or electromagnetic radiation | It is the absorption of unloose energy past times atoms or molecules followed past times delayed emission of electromagnetic radiation |
The emission of radiations or low-cal all of a abrupt stops on removal of rootage of excitation | The emission of radiations remains for unopen to fourth dimension fifty-fifty afterward the removal of rootage of excitation |
In Fluorescence, the excited atom has comparatively curt life fourth dimension earlier its transition to depression unloose energy state | In Phosphorescence, the excited atom has comparatively long life fourth dimension earlier its transition to depression unloose energy state |
The fourth dimension menstruum or interval betwixt the absorption in addition to emission of unloose energy is really short | The fourth dimension menstruum or interval betwixt the absorption in addition to emission of unloose energy is comparatively long |
Absorption procedure occurs over curt fourth dimension interval in addition to involves the transition from solid soil country to singlet excited country in addition to create non modify the direction of the spin. | Phosphorescence involves the transition from the unmarried solid soil unloose energy country to excited triplet country in addition to involving a modify of spin state |
The emitted photon (light) has lower unloose energy than the absorbed photon in addition to emission occurs at a longer wavelength than the incident light | The emitted photon (light) has lower unloose energy than the absorbed photon in addition to emission occurs at a longer wavelength than fluorescence |
In fluorescent materials, gives an ‘an immediate flash or afterglow’ on excitation | Phosphorescent materials appears to 'glow inwards the dark', because of ho-hum emission of low-cal over time. |
Examples of Fluorescence: Gemstones fluoresce, including gypsum, talc. Jelly fish, chlorophyll extract, vitamins etc | Examples of Phosphorescence: Glow of clock dial or toys or inwards bulbs afterward switching off the low-cal inwards the room. The glow remains for unopen to minutes or fifty-fifty hours inwards a dark room Phosphorescent materials inwards sign board illuminate during night. |
0 comments
Post a Comment